Tag Organic Reaction Toolbox

Articles by tag "Organic Reaction Toolbox"

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  1. Benzoyl Peroxide (BPO) Benzoyl peroxide is a chemical compound with structural formula (C6H5−C(=O)O−)2, often abbreviated as (BzO)2. In terms of its structure, the molecule can be described as two benzoyl (C6H5−C(=O)−, Bz) groups connected by a peroxide (−O−O−). It is a white granular solid with a faint ...
  2. Sodium Hypochlorite (NaOCl) Sodium hypochlorite is an inexpensive, strong oxidizing agent, that is used as disinfectant and bleaching agent. It is unstable as a solid, but solutions of up to 40% are commercially available that contain NaOH and NaCl as byproducts of the preparation:
  3. N-Bromosaccharin N-Bromosaccharin
  4. N-Bromosuccinimide (NBS) N-Bromosuccinimide (NBS) is a brominating and oxidizing agent that is used as source for bromine in radical reactions (for example: allylic brominations) and various electrophilic additions. The NBS bromination of substrates such as alcohols and amines, followed by elimination of HBr in the ...
  5. Burgess reagent The Burgess reagent, (Methoxycarbonylsulfamoyl)triethylammonium hydroxide is a commercially available compound that has historically found utility as a dehydrating agent. The reagent may also be used to oxidize primary and secondary alcohols to their corresponding aldehydes and ketones in ...
  6. Crotononitrile, (E)-But-2-enenitrile Crotononitrile is a good hydrogen acceptor in ruthenium-catalyzed hydrogen transfer reactions.
  7. 1-Hydrosilatrane 1-Hydrosilatrane, depicted in Figure 1, serves as a highly versatile hydride reagent. It can be employed in various reduction reactions to synthesize alcohols, amines, their chiral derivatives, and esters from aldehydes and ketones.
  8. Single-Electron Oxidation-Induced Chemical Transformations: Carbon-Carbon Bond Formation and Selective Oxaziridine Rearrangement Visible-light photoredox catalysis represents a significant and expanding research domain within the realm of eco-friendly and sustainable organic synthesis. Our group has conducted extensive research on the single-electron transfer (SET) mechanism in photoredox catalysis, aiming to develop more ...
  9. Spirocyclic Building Blocks for Scaffold Assembly Currently, chemists are becoming increasingly interested in spirocyclic building block molecules containing quaternary rings. Aladdin Scientific offers a range of spiral building block products, including various types of spiral [3.3] heptanes1 and spiral [3.4] octanes2-3. These building blocks ...
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