Potassium hexachloroiridate(IV) - technical grade, high purity , CAS No.16920-56-2

In stock
Item Number
P476867
Grouped product items
SKU Size Availability Price Qty
P476867-1g
1g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$249.90

Basic Description

Synonyms Dipotassium;tetrachloroiridium;dichloride | Iridate(2-), hexachloro-, potassium (1:2), (OC-6-11)- | AKOS015910855 | potassium chloroiridate | Dipotassium hexachloroiridate | MFCD00011369 | AKOS015833379 | POTASSIUMHEXACHLOROIRIDATE(IV) | Iridium potassium
Specifications & Purity technical grade
Grade technical grade

AI Insight

Names and Identifiers

IUPAC Name dipotassium;hexachloroiridium(2-)
INCHI InChI=1S/6ClH.Ir.2K/h6*1H;;;/q;;;;;;+4;2*+1/p-6
InChi Key WEKZJZDULNNSCD-UHFFFAOYSA-H
Canonical SMILES Cl[Ir-2](Cl)(Cl)(Cl)(Cl)Cl.[K+].[K+]
Isomeric SMILES Cl[Ir-2](Cl)(Cl)(Cl)(Cl)Cl.[K+].[K+]
WGK Germany 3
PubChem CID 11049163
Molecular Weight 483.12

Certificates(CoA,COO,BSE/TSE and Analysis Chart)

C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Chemical and Physical Properties

Melt Point(°C) >385 °C
Molecular Weight 483.100 g/mol
XLogP3
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 1
Rotatable Bond Count 0
Exact Mass 482.7 Da
Monoisotopic Mass 480.703 Da
Topological Polar Surface Area 0.000 Ų
Heavy Atom Count 9
Formal Charge 0
Complexity 62.700
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
The total count of all stereochemical bonds 0
Covalently-Bonded Unit Count 3

Safety and Hazards(GHS)

Pictogram(s) GHS07
Signal Warning
Hazard Statements

H315: Causes skin irritation

H319: Causes serious eye irritation

H335: May cause respiratory irritation

H302: Harmful if swallowed

H312: Harmful in contact with skin

H332: Harmful if inhaled

Precautionary Statements

P261: Avoid breathing dust/fume/gas/mist/vapors/spray.

P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P280: Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352: IF ON SKIN: wash with plenty of water.

P321: Specific treatment (see ... on this label).

P405: Store locked up.

P501: Dispose of contents/container to ...

P264: Wash hands [and …] thoroughly after handling.

P271: Use only outdoors or in a well-ventilated area.

P270: Do not eat, drink or smoke when using this product.

P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P403+P233: Store in a well-ventilated place. Keep container tightly closed.

P362+P364: Take off contaminated clothing and wash it before reuse.

P330: Rinse mouth.

P264+P265: Wash hands [and …] thoroughly after handling. Do not touch eyes.

P301+P317: IF SWALLOWED: Get medical help.

P317: Get emergency medical help.

P337+P317: If eye irritation persists: Get medical help.

P332+P317: If skin irritation occurs: Get medical help.

P319: Get medical help if you feel unwell.

WGK Germany 3

Specifications

Citations of This Product

1. Dan-Qing Liu, Zhouxin Luo, Bingxing Zhang, Guoqiang Zhao, Wei Guo, Jian Chen, Mingxia Gao, Yongfeng Liu, Hongge Pan, Wenping Sun.  (2022)  Tailoring Interfacial Charge Transfer of Epitaxially Grown Ir Clusters for Boosting Hydrogen Oxidation Reaction.  Advanced Energy Materials,  13  (1): (2202913).  [PMID:] [10.1002/aenm.202202913]
2. Tixuan Xia, Chunbo Liu, Yang Lu, Wei Jiang, Hongji Li, Yunchao Ma, Yuanyuan Wu, Guangbo Che.  (2022)  Regulating Ru-based double perovskite against lattice oxygen oxidation by incorporating Ir for efficient and stable acidic oxygen evolution reaction.  APPLIED SURFACE SCIENCE,  605  (154727).  [PMID:] [10.1016/j.apsusc.2022.154727]
3. Na Li, Liang Cai, Chao Wang, Yue Lin, Jinzhen Huang, Hongyuan Sheng, Haibin Pan, Wei Zhang, Qianqian Ji, Hengli Duan, Wei Hu, Wenhua Zhang, Fengchun Hu, Hao Tan, Zhihu Sun, Bo Song, Song Jin, Wensheng Yan.  (2021)  Identification of the Active-Layer Structures for Acidic Oxygen Evolution from 9R-BaIrO3 Electrocatalyst with Enhanced Iridium Mass Activity.  Journal of the American Chemical Society,  143  (43): (18001–18009).  [PMID:34694127] [10.1021/jacs.1c04087]
4. Zhong Yingying, Li Qing-lan, Lu Minglei, Wang Tiantian, Yang Huiyi, He Qiyi, Cui Xiping, Li Xiangguang, Zhao Suqing.  (2020)  A colorimetric sensing strategy based on enzyme@metal-organic framework and oxidase-like IrO2/MnO2 nanocomposite for α-glucosidase inhibitor screening.  MICROCHIMICA ACTA,  187  (12): (1-10).  [PMID:33241461] [10.1007/s00604-020-04660-6]
5. Xueyuan Wang, Jiafang Xie, Muhammad Arsalan Ghausi, Jiangquan Lv, Yiyin Huang, Maoxiang Wu, Yaobing Wang, Jiannian Yao.  (2019)  Rechargeable Zn–CO2 Electrochemical Cells Mimicking Two-Step Photosynthesis.  ADVANCED MATERIALS,  31  (17): (1807807).  [PMID:30803058] [10.1002/adma.201807807]
6. Yang Lan, Yu Guangtao, Ai Xuan, Yan Wensheng, Duan Hengli, Chen Wei, Li Xiaotian, Wang Ting, Zhang Chenghui, Huang Xuri, Chen Jie-Sheng, Zou Xiaoxin.  (2018)  Efficient oxygen evolution electrocatalysis in acid by a perovskite with face-sharing IrO6 octahedral dimers.  Nature Communications,  (1): (1-9).  [PMID:30531797] [10.1038/s41467-018-07678-w]
7. Miao Kan, Xufang Qian, Taiyang Zhang, Dongting Yue, Yixin Zhao.  (2017)  Highly Active IrOx Nanoparticles/Black Si Electrode for Efficient Water Splitting with Conformal TiO2 Interface Engineering.  ACS Sustainable Chemistry & Engineering,  (11): (10940–10946).  [PMID:] [10.1021/acssuschemeng.7b02850]

References

1. G M Kolodny,C Rose.  (1983-07-01)  Tumoricidal effects of sodium hexachloroiridate on an ascitic tumor in mice..  Cancer research,  43  ((7)): (3101-3103).  [PMID:6682698]
2. L D Kwiatkowski,M Adelman,R Pennelly,D J Kosman.  (1981-06-01)  Kinetic mechanism of the Cu(II) enzyme galactose oxidase..  Journal of inorganic biochemistry,  14  ((3)): (209-222).  [PMID:7196436]
3. Z S Farhangrazi,R Sinclair,L Powers,I Yamazaki.  (1995-11-21)  Formation of a porphyrin pi-cation radical in the fluoride complex of horseradish peroxidase..  Biochemistry,  34  ((46)): (14970-14974).  [PMID:7578110]
4. V Duarte,J G Muller,C J Burrows.  (1998-12-24)  Insertion of dGMP and dAMP during in vitro DNA synthesis opposite an oxidized form of 7,8-dihydro-8-oxoguanine..  Nucleic acids research,  27  ((2)): (496-502).  [PMID:9862971]
5. Olga Kornyushyna,Aym M Berges,James G Muller,Cynthia J Burrows.  (2002-12-18)  In vitro nucleotide misinsertion opposite the oxidized guanosine lesions spiroiminodihydantoin and guanidinohydantoin and DNA synthesis past the lesions using Escherichia coli DNA polymerase I (Klenow fragment)..  Biochemistry,  41  ((51)): (15304-15314).  [PMID:12484769]
6. Na Song,David M Stanbury.  (2008-11-14)  Proton-coupled electron-transfer oxidation of phenols by hexachloroiridate(IV)..  Inorganic chemistry,  47  ((24)): (11458-11460).  [PMID:19006385]
7. Fabrizio Testa,Daniela Mastronicola,Diane E Cabelli,Eugenio Bordi,Leopoldo P Pucillo,Paolo Sarti,Lígia M Saraiva,Alessandro Giuffrè,Miguel Teixeira.  (2011-08-16)  The superoxide reductase from the early diverging eukaryote Giardia intestinalis..  Free radical biology & medicine,  51  ((8)): (1567-1574).  [PMID:21839165]
8. Man-Song Li,Elizabeth A Cowley,Paul Linsdell.  (2012-05-23)  Pseudohalide anions reveal a novel extracellular site for potentiators to increase CFTR function..  British journal of pharmacology,  167  ((5)): (1062-1075).  [PMID:22612315]
9. Edward P Randviir,Dale A C Brownson,Maria Gómez-Mingot,Dimitrios K Kampouris,Jesús Iniesta,Craig E Banks.  (2012-09-11)  Electrochemistry of Q-graphene..  Nanoscale,  ((20)): (6470-6480).  [PMID:22961209]
10. Y Kaneko,M Tamura,I Yamazaki.  (1980-12-09)  Formation of porphyrin pi cation radical in zinc-substituted horseradish peroxidase..  Biochemistry,  19  ((25)): (5795-5799).  [PMID:6257291]
11. J G Muller,V Duarte,R P Hickerson,C J Burrows.  (1998-06-20)  Gel electrophoretic detection of 7,8-dihydro-8-oxoguanine and 7, 8-dihydro-8-oxoadenine via oxidation by Ir (IV)..  Nucleic acids research,  26  ((9)): (2247-2249).  [PMID:9547288]
12. Salah Boussaad,Bruce A Diner,Janine Fan.  (2008-03-07)  Influence of redox molecules on the electronic conductance of single-walled carbon nanotube field-effect transistors: application to chemical and biological sensing..  Journal of the American Chemical Society,  130  ((12)): (3780-3787).  [PMID:18321094]
13. Nootan Bhattarai,David M Stanbury.  (2012-11-29)  Oxidation of glutathione by hexachloroiridate(IV), dicyanobis(bipyridine)iron(III), and tetracyano(bipyridine)iron(III)..  Inorganic chemistry,  51  ((24)): (13303-13311).  [PMID:23186256]
14. Dan-Qing Liu, Zhouxin Luo, Bingxing Zhang, Guoqiang Zhao, Wei Guo, Jian Chen, Mingxia Gao, Yongfeng Liu, Hongge Pan, Wenping Sun.  (2022)  Tailoring Interfacial Charge Transfer of Epitaxially Grown Ir Clusters for Boosting Hydrogen Oxidation Reaction.  Advanced Energy Materials,  13  (1): (2202913).  [PMID:] [10.1002/aenm.202202913]
15. Tixuan Xia, Chunbo Liu, Yang Lu, Wei Jiang, Hongji Li, Yunchao Ma, Yuanyuan Wu, Guangbo Che.  (2022)  Regulating Ru-based double perovskite against lattice oxygen oxidation by incorporating Ir for efficient and stable acidic oxygen evolution reaction.  APPLIED SURFACE SCIENCE,  605  (154727).  [PMID:] [10.1016/j.apsusc.2022.154727]
16. Na Li, Liang Cai, Chao Wang, Yue Lin, Jinzhen Huang, Hongyuan Sheng, Haibin Pan, Wei Zhang, Qianqian Ji, Hengli Duan, Wei Hu, Wenhua Zhang, Fengchun Hu, Hao Tan, Zhihu Sun, Bo Song, Song Jin, Wensheng Yan.  (2021)  Identification of the Active-Layer Structures for Acidic Oxygen Evolution from 9R-BaIrO3 Electrocatalyst with Enhanced Iridium Mass Activity.  Journal of the American Chemical Society,  143  (43): (18001–18009).  [PMID:34694127] [10.1021/jacs.1c04087]
17. Zhong Yingying, Li Qing-lan, Lu Minglei, Wang Tiantian, Yang Huiyi, He Qiyi, Cui Xiping, Li Xiangguang, Zhao Suqing.  (2020)  A colorimetric sensing strategy based on enzyme@metal-organic framework and oxidase-like IrO2/MnO2 nanocomposite for α-glucosidase inhibitor screening.  MICROCHIMICA ACTA,  187  (12): (1-10).  [PMID:33241461] [10.1007/s00604-020-04660-6]
18. Xueyuan Wang, Jiafang Xie, Muhammad Arsalan Ghausi, Jiangquan Lv, Yiyin Huang, Maoxiang Wu, Yaobing Wang, Jiannian Yao.  (2019)  Rechargeable Zn–CO2 Electrochemical Cells Mimicking Two-Step Photosynthesis.  ADVANCED MATERIALS,  31  (17): (1807807).  [PMID:30803058] [10.1002/adma.201807807]
19. Yang Lan, Yu Guangtao, Ai Xuan, Yan Wensheng, Duan Hengli, Chen Wei, Li Xiaotian, Wang Ting, Zhang Chenghui, Huang Xuri, Chen Jie-Sheng, Zou Xiaoxin.  (2018)  Efficient oxygen evolution electrocatalysis in acid by a perovskite with face-sharing IrO6 octahedral dimers.  Nature Communications,  (1): (1-9).  [PMID:30531797] [10.1038/s41467-018-07678-w]
20. Miao Kan, Xufang Qian, Taiyang Zhang, Dongting Yue, Yixin Zhao.  (2017)  Highly Active IrOx Nanoparticles/Black Si Electrode for Efficient Water Splitting with Conformal TiO2 Interface Engineering.  ACS Sustainable Chemistry & Engineering,  (11): (10940–10946).  [PMID:] [10.1021/acssuschemeng.7b02850]

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